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- W1993313561 abstract "A theoretical study of the interfacial impedance between two immiscible liquids is undertaken assuming that, before being transferred from one medium to the other, the ion considered can be adsorbed at the interface. The simple corresponding model is applicable within the whole range of frequencies explored for one of the two quaternary ammonium ion studied. In the case of the other, additional complications must be taken into consideration to explain the behavior observed at low frequencies. This could be explained by the existence of two adsorption states corresponding possibly to two different orientations of the adsorbed ion. This second model forecasts a behavior approximately similar to the previous one, except in the case of the lower frequencies. The determination of several kinetic parameters with the help of the first model leads to very small values for the apparent transfer coefficient which are perfectly compatible with the results previously obtained for these type of systems. Further information could be gained by extending the region of frequencies studied toward the lower values and by comparing the spectra thus given with the concentration of the ion which is transferred." @default.
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- W1993313561 date "1979-05-01" @default.
- W1993313561 modified "2023-10-16" @default.
- W1993313561 title "On the impedance of the interface between two immiscible electrolytic solutions in the presence of an adsorbed ion soluble in both media" @default.
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- W1993313561 doi "https://doi.org/10.1016/0021-9797(79)90134-6" @default.
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