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- W1993320779 abstract "Abstract The kinetics of the dopaquinone cyclization in the absence and presence of Cu(II) ions at pHs from 6 to 7.4 has been studied by cyclic, normal and reverse pulse voltammetry. Distinct inhibition of the dopaquinone ring closure reaction was observed in the. presence of Cu(II) ions. At pHs below 6 this effect is attributed to the formation of amino acid type complexes. At pH 7.4 the amino acid type and the catechol type Cu(II)-DOPA chelates coexist, and simultaneous interactions of copper ions with both ends of the DOPA molecule result in the association of the Cu(II)-DOPA complexes. These effects, observed at physiological pH, suggest that the rate of melanin formation is affected by the presence of Cu(II) ions." @default.
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- W1993320779 date "1989-06-01" @default.
- W1993320779 modified "2023-09-26" @default.
- W1993320779 title "The effect of Cu(II) ions on dopaquinone cyclization" @default.
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