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- W1993348747 abstract "Abstract A series of 3,3-disubstituted bicyclic anhydro-4-hydroxy-2-oxo-1,3-thiazinium hydroxides are easily prepared from the reaction of 3H-thiolactams with 1,3-bielectrophiles. These cross-conjugated heteroaromatic betaines undergo regio- and diastereospecific 1,4-dipolar cycloaddition with electron-rich and electron-deficient π-bonds to produce 1,4-cycloadducts containing a carbonyl sulfide bridge. A representative betaine dipole and a 1,4-cycloadduct were characterized by single crystal X-ray determinations. In certain cases, the initially formed cycloadduct can be induced to lose COS on further heating. The frontier orbital coefficients of the thiazinium betaine were determined by semi-empirical MOPAC calculations with the PM3 Hamiltonian. The HOMO of the 1,4-dipole is dominant for reactions with electron-deficient dipolarophiles such as N-phenylmaleimide, while the LUMO becomes important for cycloaddition to more electron-rich species such as ynamines or vinyl ethers." @default.
- W1993348747 created "2016-06-24" @default.
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- W1993348747 date "2010-08-17" @default.
- W1993348747 modified "2023-09-25" @default.
- W1993348747 title "ChemInform Abstract: Details Associated with the Bimolecular 1,4-Dipolar Cycloaddition Reaction of Cross-Conjugated Heteroaromatic Betaines." @default.
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- W1993348747 doi "https://doi.org/10.1002/chin.199542042" @default.
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