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- W1993351570 abstract "Excitation spectra for Tb 3+ and Ce 3+ as well as fluorescence spectra for Ce 3+ due to 4 f -5 d transitions in calcite-type borates have been measured at liquid helium temperature. Sharp no-phonon lines are accompanied by phonon sidebands extending over 3500 cm -1 . The vibronic sidebands are considered to reflect vibrations of pure lattices. The spin-allowed 4 f -5 d transitions of Tb 3+ and Ce 3+ are accompanied by phonon sidebands due to even-parity lattice vibrations. The spin-forbidden 4 f -5 d vibronic sidebands of Tb 3+ are due to odd-parity lattice vibrations. Models of the coupling schemes of the 4 f 7 5 d and 5 d configurations in the crystal field are presented. A comparison of the observed spectra with the models suggests that the 5 d electron may not see the trigonal component of the crystal field. Transition matrix elements between the ground 4 f state and the Stark components of the excited 5 d states of Ce 3+ are calculated." @default.
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- W1993351570 date "1972-03-01" @default.
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- W1993351570 title "4<i>f</i>-5<i>d</i> Transitions of Tb<sup>3+</sup> and Ce<sup>3+</sup> in Calcite-Type MBO<sub>3</sub>(M=Sc, In and Lu)" @default.
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- W1993351570 doi "https://doi.org/10.1143/jpsj.32.771" @default.
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