Matches in SemOpenAlex for { <https://semopenalex.org/work/W1993370310> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1993370310 endingPage "3294" @default.
- W1993370310 startingPage "3287" @default.
- W1993370310 abstract "The compound Re2O7, Re2O7·2H2O or [ReO3(OSiMe3)] reacted with H2diol to form complexes having the general formula [ReO3(Hdiol)] where H2diol = 2,3-dimethylbutane-2,3-diol (H2pin) or 1,1′-bicyclohexane-1,1′-diol (H2bicy). In the case of H2pin the complex [ReO3(Hpin)]·H2pin is formed initially in the reaction of rhenium(VII) oxides with an excess of pinacol. The hydrogen bonded free pinacol molecule can be removed by sublimation. The monomethyl derivative of pinacol, HMepin, reacts in a similar way to form the complex [ReO3(Mepin)]. In the rhenium(VII) compounds the Re atom has a distorted trigonal bipyramidal co-ordination geometry. Pale yellow solutions of [ReO3(Hdiol)] in CH2Cl2 slowly become orange and red crystals having the formula [ReO(diol)2] may be isolated. The reaction of rhenium(VII) oxides with H2diol and PPh3 in the presence of drying agents in CH2Cl2 produced the same compounds in high yield. The crystal structures of the rhenium(VI) complexes reveal that the rhenium(VI) cations have square pyramidal co-ordination geometries. The rhenium(VI) oxo bis(diolato) complexes are thermally stable and do not readily undergo oxidation in dry air." @default.
- W1993370310 created "2016-06-24" @default.
- W1993370310 creator A5015216114 @default.
- W1993370310 creator A5023819252 @default.
- W1993370310 creator A5069668948 @default.
- W1993370310 creator A5088223479 @default.
- W1993370310 date "1998-01-01" @default.
- W1993370310 modified "2023-09-26" @default.
- W1993370310 title "Preparation and reactions of rhenium(VII) trioxo hydrogendiolato complexes and rhenium(VI) oxo bis(diolato) complexes" @default.
- W1993370310 cites W1523785197 @default.
- W1993370310 cites W1990595546 @default.
- W1993370310 cites W1996455423 @default.
- W1993370310 cites W1996564659 @default.
- W1993370310 cites W2000723485 @default.
- W1993370310 cites W2008879314 @default.
- W1993370310 cites W2011072724 @default.
- W1993370310 cites W2023734678 @default.
- W1993370310 cites W2027102424 @default.
- W1993370310 cites W2059020082 @default.
- W1993370310 cites W2059401704 @default.
- W1993370310 cites W2063420984 @default.
- W1993370310 cites W2083339236 @default.
- W1993370310 cites W2951839344 @default.
- W1993370310 cites W2952295036 @default.
- W1993370310 cites W2953171722 @default.
- W1993370310 doi "https://doi.org/10.1039/a803301c" @default.
- W1993370310 hasPublicationYear "1998" @default.
- W1993370310 type Work @default.
- W1993370310 sameAs 1993370310 @default.
- W1993370310 citedByCount "14" @default.
- W1993370310 countsByYear W19933703102014 @default.
- W1993370310 countsByYear W19933703102015 @default.
- W1993370310 countsByYear W19933703102016 @default.
- W1993370310 countsByYear W19933703102017 @default.
- W1993370310 countsByYear W19933703102018 @default.
- W1993370310 crossrefType "journal-article" @default.
- W1993370310 hasAuthorship W1993370310A5015216114 @default.
- W1993370310 hasAuthorship W1993370310A5023819252 @default.
- W1993370310 hasAuthorship W1993370310A5069668948 @default.
- W1993370310 hasAuthorship W1993370310A5088223479 @default.
- W1993370310 hasConcept C111592845 @default.
- W1993370310 hasConcept C115624301 @default.
- W1993370310 hasConcept C155647269 @default.
- W1993370310 hasConcept C161790260 @default.
- W1993370310 hasConcept C178790620 @default.
- W1993370310 hasConcept C179104552 @default.
- W1993370310 hasConcept C185592680 @default.
- W1993370310 hasConcept C2776230795 @default.
- W1993370310 hasConcept C2776730140 @default.
- W1993370310 hasConcept C2781083472 @default.
- W1993370310 hasConcept C505216180 @default.
- W1993370310 hasConcept C544153396 @default.
- W1993370310 hasConceptScore W1993370310C111592845 @default.
- W1993370310 hasConceptScore W1993370310C115624301 @default.
- W1993370310 hasConceptScore W1993370310C155647269 @default.
- W1993370310 hasConceptScore W1993370310C161790260 @default.
- W1993370310 hasConceptScore W1993370310C178790620 @default.
- W1993370310 hasConceptScore W1993370310C179104552 @default.
- W1993370310 hasConceptScore W1993370310C185592680 @default.
- W1993370310 hasConceptScore W1993370310C2776230795 @default.
- W1993370310 hasConceptScore W1993370310C2776730140 @default.
- W1993370310 hasConceptScore W1993370310C2781083472 @default.
- W1993370310 hasConceptScore W1993370310C505216180 @default.
- W1993370310 hasConceptScore W1993370310C544153396 @default.
- W1993370310 hasIssue "19" @default.
- W1993370310 hasLocation W19933703101 @default.
- W1993370310 hasOpenAccess W1993370310 @default.
- W1993370310 hasPrimaryLocation W19933703101 @default.
- W1993370310 hasRelatedWork W1969881774 @default.
- W1993370310 hasRelatedWork W1979760013 @default.
- W1993370310 hasRelatedWork W1993370310 @default.
- W1993370310 hasRelatedWork W2001958576 @default.
- W1993370310 hasRelatedWork W2018115285 @default.
- W1993370310 hasRelatedWork W2043246249 @default.
- W1993370310 hasRelatedWork W2059701585 @default.
- W1993370310 hasRelatedWork W2064756905 @default.
- W1993370310 hasRelatedWork W2761962751 @default.
- W1993370310 hasRelatedWork W2803492 @default.
- W1993370310 isParatext "false" @default.
- W1993370310 isRetracted "false" @default.
- W1993370310 magId "1993370310" @default.
- W1993370310 workType "article" @default.