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• W1993373251 abstract "A chemical reaction of CrO3 with polymer molecules of poly vinyl alcohol (PVA) and sucrose in water is explored to synthesize CrO2 (D4h14:P42/mnm tetragonal crystal structure) of shape-controlled ferromagnetic particles. Under hot conditions, small species of Cr6+–PVA polymer chelates react in divided groups in micelles, resulting in a Cr4+–polymer complex, which retains in isolated groups of micelles dispersed in the water. When heating (after aging and drying), the polymer burns out at 300–400 °C in air, leaving behind a pure CrO2 of prismatic or ellipsoidal shape. Average diameter varies in such particles from 50 to 300 nm depending on the final temperature." @default.
• W1993373251 created "2016-06-24" @default.
• W1993373251 creator A5001419863 @default.
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• W1993373251 date "2006-11-01" @default.
• W1993373251 modified "2023-09-23" @default.
• W1993373251 title "Synthesis of shape-controlled ferromagnetic CrO2 nanoparticles by reaction in micelles of Cr6+–PVA polymer chelates" @default.
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• W1993373251 doi "https://doi.org/10.1016/j.matchemphys.2005.11.031" @default.
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