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- W1993375982 abstract "The treatment of N-benzylideneaniline (1a) with a half-equivalent of lanthanum metal and a catalytic amount of iodine gave the reductive dimerization product of 1a, a vic-diamine, in good yield. Various vic-diamines were synthesized from aldimines in this manner in moderate to good yields. Our findings suggest that electrons of a zero-valent lanthanum metal were efficiently utilized in this reductive dimerization. In the reaction of ketimines, however, a similar reductive dimerization did not take place, and the corresponding amines were formed as the sole products. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:131–135, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10007" @default.
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- W1993375982 date "2010-05-20" @default.
- W1993375982 modified "2023-09-26" @default.
- W1993375982 title "ChemInform Abstract: Reductive Dimerization and Reduction of Imines Using Lanthanum Metal." @default.
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- W1993375982 doi "https://doi.org/10.1002/chin.200230059" @default.
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