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• W1993397075 abstract "The complex [Pd(κ2-P,O-{2-(2-MeOC6H4)2P}C6H4SO3)Me(dmso)] (1) is investigated for the copolymerization of (E) with norbornene (N) and functionalized N derivatives affording P(E-co-N) in excellent yields. Copolymer molar masses are higher than those of PE and increase with N concentration. In addition, the complex [Ti(κ2-N,O-{2,6-F2C6H3N = C(Me)C(H) = C(CF3)O})2Cl2] (2) is evaluated as catalyst for living E-co-N copolymerization upon activation with dried methylaluminoxane between 25 and 90 °C. Copolymerization at different [N]/[E] feed ratios affords stereoirregular alternating high molar mass P(E-co-N) with narrow molar mass distribution. P(E-co-N) living copolymerization is demonstrated by kinetics at 50 °C. Block copolymers are synthesized and fully characterized." @default.
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• W1993397075 date "2012-12-13" @default.
• W1993397075 modified "2023-10-03" @default.
• W1993397075 title "Cycloolefin Copolymers by Early and Late Transition Metal Catalysts" @default.
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• W1993397075 doi "https://doi.org/10.1002/mren.201200056" @default.
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