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- W1993400152 abstract "Controlled inhibition of the enzyme Cu/Zn superoxide dismutase (SOD), one of the most important enzymes of the antioxidant defense system of aerobic organisms, is the subject of this paper. It is desirable in several noted medical and agricultural applications. This paper describes the synthesis of a very limited “sublibrary” of bifunctional metal chelators. The first function is the metal chelator DTC (sodium diethyldithiocarbamate (Et2DTC)), which has the sole chemical function of specific metal binding. An amphiphile (more precisely, an oligoether) is the second function and has a sole physical function: changing the physical properties of the molecule. The paper discusses novel copper chelators with variable amphiphilic properties: disubstituted dithiocarbamates (DTCs, R1(CH2CH2O)2NR2CS2Na) with one alkyl (R2 = hexyl, octyl, decyl, or dodecyl) and one oligoether (R1(CH2CH2O)2, where R1 = Et or Bu) substituent. The octanol−water distribution ratios of the dithiocarbamates (partition measurements by t..." @default.
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- W1993400152 date "2001-08-09" @default.
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- W1993400152 title "Copper-Specific Chelators as Synergists to Herbicides: 1. Amphiphilic Dithiocarbamates, Synthesis, Transport through Lipid Bilayers, and Inhibition of Cu/Zn Superoxide Dismutase Activity" @default.
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- W1993400152 doi "https://doi.org/10.1021/la010299e" @default.
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