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• W1993427153 endingPage "14433" @default.
• W1993427153 startingPage "14422" @default.
• W1993427153 abstract "The synthesis and characterization of four low-spin (carbonyl)iron(II) tetraphenylporphyrinates, [Fe(TPP)(CO)(L)], where L = 1-methylimidazole, 2-methylimidazole, 1,2-dimethylimidazole (unsolvated), and 1,2-dimethylimidazole (toluene solvate) are reported. The complexes show nearly the same value of νC-O in toluene solution (1969−72 cm-1) but a large range of CO stretching frequencies in the solid-state (1926−1968 cm-1). The large solid-state variation results from CO interactions in the solid state, as shown by an examination of the crystal structures of the four complexes. The high precision of the four structures obtained allows us to make a number of structural and spectroscopic correlations that describe the Fe−C−O and NIm-Fe−CO units. The values of νC-O and the Fe−C and C−O bond distances are strongly correlated and provide a structural, as well as a spectroscopic, correlation of the π back-bonding model. The interactions of CO described are closely related to the large range of CO stretching frequencies observed in heme proteins and specific interactions observed in carbonylmyoglobin (MbCO)." @default.
• W1993427153 created "2016-06-24" @default.
• W1993427153 creator A5016476989 @default.
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• W1993427153 creator A5042330605 @default.
• W1993427153 creator A5086933086 @default.
• W1993427153 date "2005-09-27" @default.
• W1993427153 modified "2023-09-23" @default.
• W1993427153 title "Heme Carbonyls: Environmental Effects on ν_C_-_O and Fe−C/C−O Bond Length Correlations" @default.
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• W1993427153 doi "https://doi.org/10.1021/ja053148x" @default.
• W1993427153 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/1866288" @default.
• W1993427153 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16218637" @default.
• W1993427153 hasPublicationYear "2005" @default.
• W1993427153 type Work @default.

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