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- W1993469265 abstract "Solutions of 2-diphenyl- or 2-dicyclohexylphosphinophenol, nickel bis(1,5-cyclooctadiene), and a tertiary phosphine R 3 P in toluene oligomerize ethylene in most cases with high selectivity to linear α -olefins. The molecular weights can be tuned by the catalyst composition. Molecular weights are generally lower with Ph 2 P ∩ ONi than with c Hex 2 P ∩ ONi catalysts and in the presence of R 3 P additives, but basicity-dependent effects of various triarylphosphine additives on the molecular weights and relative reaction rates, displayed by pressure-time plots, are rather different or opposite for Ph 2 P ∩ ONi and c Hex 2 P ∩ ONi catalysts." @default.
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- W1993469265 date "2004-07-01" @default.
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- W1993469265 title "The impact of P substituents on the oligomerization of ethylene withBnickel 2-diphenyl and 2-dicyclohexylphosphinophenolate phosphineBcatalysts" @default.
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- W1993469265 doi "https://doi.org/10.1016/j.jcat.2004.03.029" @default.
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