Matches in SemOpenAlex for { <https://semopenalex.org/work/W1993505514> ?p ?o ?g. }
- W1993505514 endingPage "16581" @default.
- W1993505514 startingPage "16581" @default.
- W1993505514 abstract "Using a combination of experiments and density functional theory (DFT) calculations, we explored the mechanisms of the stabilization effect of the thiolized (–SH) group on the Pt/SH-CNTs catalyst. Pt particles supported on the hydroxyl functionalized CNTs (Pt/OH-CNTs) are synthesized as a baseline for comparison. Experimentally, the platinum on OH-CNTs has a stronger tendency for aggregation than that on SH-CNTs. The differences in the oxidation resistance, migration activation energy, and corrosion resistance between the Pt/SH-CNTs and Pt/OH-CNTs are calculated using DFT. The DFT calculations indicate that the –SH group enhances the oxidation resistance of the Pt cluster and CNTs and restricts Pt migration on the CNTs. DFT calculations also suggest that the enhanced stability of Pt/SH-CNTs originates from the increased interaction between Pt and SH-CNTs and the depressed d-band center of the Pt NPs. Thus, the functional groups on the CNTs used for stabilization of supported Pt NPs should provide a deposit and anchor site for Pt NPs and maintain the perfect structure of CNTs rather than destroying it." @default.
- W1993505514 created "2016-06-24" @default.
- W1993505514 creator A5027105361 @default.
- W1993505514 creator A5030828863 @default.
- W1993505514 creator A5033779961 @default.
- W1993505514 creator A5077599720 @default.
- W1993505514 creator A5086994491 @default.
- W1993505514 creator A5091123209 @default.
- W1993505514 date "2012-01-01" @default.
- W1993505514 modified "2023-10-16" @default.
- W1993505514 title "Experimental and DFT study of thiol-stabilized Pt/CNTs catalysts" @default.
- W1993505514 cites W1965752441 @default.
- W1993505514 cites W1966750682 @default.
- W1993505514 cites W1967360813 @default.
- W1993505514 cites W1971019017 @default.
- W1993505514 cites W1973836541 @default.
- W1993505514 cites W1974374981 @default.
- W1993505514 cites W1977797818 @default.
- W1993505514 cites W1989396636 @default.
- W1993505514 cites W1990553848 @default.
- W1993505514 cites W1991803078 @default.
- W1993505514 cites W1992385763 @default.
- W1993505514 cites W1992713596 @default.
- W1993505514 cites W1994018546 @default.
- W1993505514 cites W1998981251 @default.
- W1993505514 cites W2001841788 @default.
- W1993505514 cites W2011083092 @default.
- W1993505514 cites W2011257182 @default.
- W1993505514 cites W2011864591 @default.
- W1993505514 cites W2016791969 @default.
- W1993505514 cites W2017937844 @default.
- W1993505514 cites W2022543222 @default.
- W1993505514 cites W2023705735 @default.
- W1993505514 cites W2030778826 @default.
- W1993505514 cites W2032954152 @default.
- W1993505514 cites W2036890837 @default.
- W1993505514 cites W2042974205 @default.
- W1993505514 cites W2048807806 @default.
- W1993505514 cites W2049672559 @default.
- W1993505514 cites W2063392900 @default.
- W1993505514 cites W2080908656 @default.
- W1993505514 cites W2086033757 @default.
- W1993505514 cites W2086697786 @default.
- W1993505514 cites W2094519492 @default.
- W1993505514 cites W2105982022 @default.
- W1993505514 cites W2106664196 @default.
- W1993505514 cites W2119237843 @default.
- W1993505514 cites W2126985437 @default.
- W1993505514 cites W2127847915 @default.
- W1993505514 cites W2145995412 @default.
- W1993505514 cites W2153304178 @default.
- W1993505514 cites W2160382754 @default.
- W1993505514 cites W2164008457 @default.
- W1993505514 cites W2171082064 @default.
- W1993505514 cites W2171614186 @default.
- W1993505514 cites W2321080053 @default.
- W1993505514 cites W2782759913 @default.
- W1993505514 cites W4239418311 @default.
- W1993505514 cites W4376453188 @default.
- W1993505514 doi "https://doi.org/10.1039/c2cp41346a" @default.
- W1993505514 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22864279" @default.
- W1993505514 hasPublicationYear "2012" @default.
- W1993505514 type Work @default.
- W1993505514 sameAs 1993505514 @default.
- W1993505514 citedByCount "26" @default.
- W1993505514 countsByYear W19935055142013 @default.
- W1993505514 countsByYear W19935055142014 @default.
- W1993505514 countsByYear W19935055142015 @default.
- W1993505514 countsByYear W19935055142016 @default.
- W1993505514 countsByYear W19935055142017 @default.
- W1993505514 countsByYear W19935055142018 @default.
- W1993505514 countsByYear W19935055142019 @default.
- W1993505514 countsByYear W19935055142020 @default.
- W1993505514 countsByYear W19935055142021 @default.
- W1993505514 countsByYear W19935055142022 @default.
- W1993505514 countsByYear W19935055142023 @default.
- W1993505514 crossrefType "journal-article" @default.
- W1993505514 hasAuthorship W1993505514A5027105361 @default.
- W1993505514 hasAuthorship W1993505514A5030828863 @default.
- W1993505514 hasAuthorship W1993505514A5033779961 @default.
- W1993505514 hasAuthorship W1993505514A5077599720 @default.
- W1993505514 hasAuthorship W1993505514A5086994491 @default.
- W1993505514 hasAuthorship W1993505514A5091123209 @default.
- W1993505514 hasConcept C127413603 @default.
- W1993505514 hasConcept C147597530 @default.
- W1993505514 hasConcept C152365726 @default.
- W1993505514 hasConcept C161790260 @default.
- W1993505514 hasConcept C171250308 @default.
- W1993505514 hasConcept C178790620 @default.
- W1993505514 hasConcept C185592680 @default.
- W1993505514 hasConcept C192562407 @default.
- W1993505514 hasConcept C42360764 @default.
- W1993505514 hasConcept C513720949 @default.
- W1993505514 hasConcept C518104683 @default.
- W1993505514 hasConceptScore W1993505514C127413603 @default.
- W1993505514 hasConceptScore W1993505514C147597530 @default.
- W1993505514 hasConceptScore W1993505514C152365726 @default.
- W1993505514 hasConceptScore W1993505514C161790260 @default.