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• W1993553539 abstract "A carbon-supported palladium catalyst modified by non-metal phosphorus (PdP/C) has been developed as an oxygen reduction catalyst for direct methanol fuel cells. The PdP/C catalyst was prepared by the sodium hypophosphite reduction method. The as-prepared Pd nanoparticles have a narrow size distribution with an average diameter of 2 nm. Energy dispersive X-ray analysis (EDX), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) results indicate that P enters into the crystal lattice of Pd and forms an alloy. The PdP/C catalyst has an oxygen reduction reaction (ORR) activity comparable to the commercial Pt/C catalyst and a higher activity than the Pd/C catalyst synthesized by the conventional NaBH4 reduction method. Its high catalytic activity can be attributed to its small size, lower relative crystallinity, and the formation of PdP alloy." @default.
• W1993553539 created "2016-06-24" @default.
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• W1993553539 date "2008-07-01" @default.
• W1993553539 modified "2023-10-16" @default.
• W1993553539 title "Carbon-supported Pd nanocatalyst modified by non-metal phosphorus for the oxygen reduction reaction" @default.
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• W1993553539 doi "https://doi.org/10.1016/j.jpowsour.2008.04.024" @default.
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