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- W1993572655 abstract "Abstract We found a series of superconducting phases in the Tl-Ba-Ca-Cu-O system and determined the crystal structures of these superconducting phases by means of the X-ray powder diffraction method. All of these superconducting phases belong to the tetragonal symmetry. They have the same lattice constant a and different lattice constant c . These superconducting phases can be divided into two types. The space group of type I is P4/mmm. The space group of type II is 14/mmm. The chemical formulae of type I and type II can be generalized as TlBa 2 Ca n −1 Cu n O 2 n +2.5 ( n =2, 3, 4) and Tl 2 Ba 2 Ca n −1 Cu n O 2 n +4 ( n =1, 2, 3), respectively. T c increases as n increases. On the condition that n is the same, type II has a higher T c than type I. The relations among the crystal structures of the superconducting phases are discussed. We proposed a method which can deduce the crystal structure of the superconducting phase from the d 1 -value of the first diffraction line (00 l ) or lattice parameter c and which is confirmed by experimental data." @default.
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- W1993572655 date "1988-11-01" @default.
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- W1993572655 title "Crystal structures and superconductivity of superconducting phases in the Tl-Ba-Ca-Cu-O system" @default.
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- W1993572655 doi "https://doi.org/10.1016/0921-4534(88)90031-7" @default.
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