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• W1993578215 startingPage "1104" @default.
• W1993578215 abstract "Geminal bis(silyl) enal 2a is shown to be a useful scaffold for anion relay chemistry (ARC) aimed at the stereoselective synthesis of C3,O1-disilylated allylic alcohols. The ARC reaction is initiated by the addition of an alkyllithium to the aldehyde and features a CuCN-promoted Csp2-to-O 1,4-silyl migration to generate a vinylcuprate that reacts with activated electrophiles." @default.
• W1993578215 created "2016-06-24" @default.
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• W1993578215 date "2013-02-15" @default.
• W1993578215 modified "2023-09-27" @default.
• W1993578215 title "Geminal Bis(silyl) Enal: A Versatile Scaffold for Stereoselective Synthesizing C³,O¹-Disilylated Allylic Alcohols Based upon Anion Relay Chemistry" @default.
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• W1993578215 doi "https://doi.org/10.1021/ol400145z" @default.
• W1993578215 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23410199" @default.
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