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- W1993647365 abstract "Rare earth-K-(S)-BINOL complexes were used to catalyze the nitroaldol reaction of the CD-ring 24-aldehyde precursors with 2-nitropropane in a good stereoselective manner. The obtained nitroaldol compound was easily converted into a synthetic intermediate 12 of 1α,24(R)-dihydroxyvitamin D31 by a denitration reaction using 2,2′-azobisisobutyronitrile (AIBN) and Bu3SnH." @default.
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- W1993647365 date "1997-08-01" @default.
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- W1993647365 title "Novel synthetic approach to 1α,24(R)-dihydroxyvitamin D3 using an asymmetric nitroaldol reaction" @default.
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- W1993647365 doi "https://doi.org/10.1016/s0957-4166(97)00312-1" @default.
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