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- W1993652988 abstract "Abstract The CO substitution reaction of Re 2 (CO) 10 with Ph 2 PCH 2 CH 2 PPh 2 in the presence of (C 2 H 5 ) 3 NO as an oxygen atom transfer reagent affords a novel substituted metal carbonyl complex of formula Re 2 Cl 2 (CO) 6 (Ph 2 PCH 2 CH 2 PPh 2 ), in which the chlorine is presumably extracted from the solvent CHCl 3 . An X-ray crystallographic analysis of the new complex has provided evidence for two chlorine and one diphosphine ligands bridging two rhenium atoms, Re(1) and Re(2), coordinated to three terminal COs, respectively." @default.
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- W1993652988 date "1992-01-01" @default.
- W1993652988 modified "2023-09-27" @default.
- W1993652988 title "Synthesis and x-ray crystal structure of [Re2(μ-Cl)2(CO)6(μ-Ph2PCH2CH2PPh2)]" @default.
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- W1993652988 doi "https://doi.org/10.1016/s0277-5387(00)83567-6" @default.
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