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- W1993666442 abstract "Various morphologies including spherical micelles, nanowires and vesicles have been prepared by reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization of styrene (St) in methanol using S-1-dodecyl-S -(α,α′-dimethyl-α″-acetic acid) trithiocarbonate (TC)-terminated poly(ethylene oxide) (PEO-TC) and 2,2′-azobis(isobutyronitrile) (AIBN) as chain transfer agent and initiator, respectively. GPC, 1H NMR, TEM and laser light scattering (LLS) were used to track the polymerization. The results showed that the block copolymers PEO-b-polystyrene (PEO-b-PS) were formed firstly in homogenous polymer solution, and then the spherical micelles were produced via polymerization-induced self-assembling. Continuous polymerization of the PS blocks induced the transition of spherical micelles into other morphologies. The polymerization-induced self-assembling and reorganization (PISR) were induced by chain length ratio increase of PS to PEO blocks. The concentration of St in methanol is also important factor to influence the formation of morphologies." @default.
- W1993666442 created "2016-06-24" @default.
- W1993666442 creator A5007152167 @default.
- W1993666442 creator A5015309843 @default.
- W1993666442 date "2010-10-01" @default.
- W1993666442 modified "2023-10-17" @default.
- W1993666442 title "Direct preparation of vesicles from one-pot RAFT dispersion polymerization" @default.
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- W1993666442 doi "https://doi.org/10.1016/j.polymer.2010.08.056" @default.
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