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- W1993670351 abstract "Abstract The title compound and its fragments after the collision activated dissociation are investigated under mass spectrometric conditions (FT‐ICR) in order to detect intermediates during the subsequent reaction with a large excess of Cl 2 . All fragments perform similar reactions: the elimination of two molecules GaCl, e. g. [Ga 13 (GaR) 4 ] − + Cl 2 → [Ga 11 (GaR) 4 ] − + 2 GaCl like a mechanism recently described for the chlorination of [Al 13 ] − clusters. In contrast, the parent ion [Ga 13 (GaR) 6 ] − exhibits a completely different sequence: only one GaCl is eliminated and the other Cl atom of each reacting Cl 2 molecule stabilizes the cluster surface: e.g. [Ga 13 (GaR) 6 ] − + Cl 2 → [Ga 12 (GaClR)(GaR) 6 ] − + GaCl. Finally, [Ga 12 R 6 Cl 6 ] − results. Surprisingly, this cluster ion does not obey the Wade rule (with an icosahedral Ga 12 core); instead an isomer is formed containing an octahedral Ga 6 entity which is surrounded by a protecting (GaRCl) 6 surface. This unexpected result is casting a light on the mechanism of every oxidation process of metal clusters, nanoparticles, and metal surfaces. Furthermore it provides a challenge to investigate the limits of Wade's rules." @default.
- W1993670351 created "2016-06-24" @default.
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- W1993670351 date "2007-04-10" @default.
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- W1993670351 title "[Ga<sub>19</sub>R<sub>6</sub>]<sup>−</sup> (R = C(SiMe<sub>3</sub>)<sub>3</sub>: A Structurally Characterized Metalloid Cluster Ion and its Stepwise Chlorination in the Gas Phase – a Model Reaction for the Oxidation of Metal‐Nanoparticles?" @default.
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- W1993670351 doi "https://doi.org/10.1002/zaac.200700032" @default.
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