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- W1993697287 abstract "The photolysis of hexacarbonyltungsten (I) in carbon tetrachloride yields a catalytic mixture for olefin metathesis. One of the principal products of this transformation is dichlorotetracarbonyltungsten (II). Chemical preparation of II from I and chlorine was carried out. Authentic II was shown to give catalysis of 2-pentene metathesis by either heating in chlorobenzene or chloroform or irradiation in chlorobenzene or carbon tetrachloride. The Dubois report of phosgene formation in the original irradiated mixture of I in carbon tetrachloride was shown to be an artifact." @default.
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- W1993697287 date "1975-10-01" @default.
- W1993697287 modified "2023-09-26" @default.
- W1993697287 title "Dichlorotetracarbonyltungsten as a catalyst for olefin metathesis" @default.
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- W1993697287 doi "https://doi.org/10.1016/s0022-328x(00)86301-9" @default.
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