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- W1993706906 abstract "The kinetics and stereochemistry of the protonation-induced unimolecular isomerization of (R)-1-D1-3-(p-fluorophenyl)butane have been investigated in the gas phase at 40−100 °C and 70−760 Torr. This process leads to the formation of the relevant meta and ortho isomers with partial racemization of the migrating sec-butyl moiety. Complete racemization is observed, instead, when the isomerization reaction involves a 1,2-H shift in the moving alkyl group. These results, together with the relevant activation parameters, fully confirm the previous evidence of the occurrence in the alkyl cation/arene PES of noncovalent η-type intermediates of defined structure and stability, lying well below the classical π-complexes, as confirmed by ab initio calculations. Their crucial role in determining the positional selectivity of gas-phase electrophilic aromatic substitutions clearly emerges from the comparison of the present results with the site selectivity measured in the corresponding bimolecular arene alkylation carried out at the same temperatures and pressures." @default.
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- W1993706906 date "2005-04-19" @default.
- W1993706906 modified "2023-10-03" @default.
- W1993706906 title "Crucial Role of Elusive Isomeric η-Complexes in Gas-Phase Electrophilic Aromatic Alkylations" @default.
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- W1993706906 doi "https://doi.org/10.1021/jo050019q" @default.
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