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• W1993716917 abstract "The reduction of representative alkyl aryl (E)-ketoxime O-benzyl ethers with borane catalyzed by terpene oxazaborolidines, derived from (1R)-nopinone and (1R)-camphor, gave the corresponding amines with 82–99% ee. Oxazaborolidines derived from (1S)-2-carene and (1S)-3-carene were less selective. (S)-1-(3-Methoxyphenyl)ethanamine (94% ee) the key intermediate in the synthesis of (S)-rivastigmine, was obtained by the reduction of (E)-1-(3-methoxyphenyl)ethanone O-benzyl oxime with borane/oxazaborolidine generated from (S)-valinol." @default.
• W1993716917 created "2016-06-24" @default.
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• W1993716917 date "2012-05-01" @default.
• W1993716917 modified "2023-09-27" @default.
• W1993716917 title "Enantioselective reduction of ketoxime ethers with borane–oxazaborolidines and synthesis of the key intermediate leading to (S)-rivastigmine" @default.
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• W1993716917 doi "https://doi.org/10.1016/j.tetasy.2012.05.008" @default.
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