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• W1993721022 startingPage "1560" @default.
• W1993721022 abstract "Metal-catalyzed reactions of ynimides with alcohols to afford β-ketoimides and oxazoles are demonstrated. The triple bond of ynamides is generally activated by mineral acids or metal salts to lead to the regioselective addition of nucleophiles at the α-C-atom, because of the inherent electronic bias. In contrast, the two neighboring carbonyl groups of ynimides decrease the electron density of the triple bond and the nucleophiles attack the carbonyl C-atom." @default.
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• W1993721022 date "2013-03-15" @default.
• W1993721022 modified "2023-09-24" @default.
• W1993721022 title "Ag- and Au-Catalyzed Addition of Alcohols to Ynimides: β-Regioselective Carbonylation and Production of Oxazoles" @default.
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• W1993721022 doi "https://doi.org/10.1021/ol400338x" @default.
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