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- W1993722204 abstract "High-resolution capillary gas chromatography (HRGC) with an isomeric selective liquid crystal as stationary phase permits a better separation of the seventeen possiblen-nonadecene isomersn-nonadecane than a separation system with a non-mesogenic stationary phase. For the identification of the separated isomers structure-retention correlations based on extrapolation of the dependence of homomorphous factors on the number of carbon atoms for homologous series ofn-alkenes and the different temperature dependences of the retention indices of geometrical isomers were used. Identification was confirmed by a combination of HRGC with Fourier transform infrared and mass spectrometric detection on the basis of infrared spectra which are distinctly different for the geometrical isomers. The rule of the alternation retention ofcis- andtrans-alkenes with an odd number of carbon atoms separated on a mesogenic stationary phase was reformulated." @default.
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- W1993722204 date "1992-09-01" @default.
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- W1993722204 title "Separation and identification of all isomericn-nonadecenes by capillary gas chromatography on a mesogenic stationary phase with Fourier transform infrared and mass spectrometric detection" @default.
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