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• W1993777202 abstract "When sampled by laser irradiation from a suitable matrix, cationized sugars can be desorbed in far higher yields for longer periods than in experiments which do not employ a matrix. Daughter spectra reveal that Li+ reacts differently from the other alkali ions in that it can catalyse ring opening; collision-induced dissociation then causes successive CC cleavage reactions. Selectivity is also exhibited by the substrate; some isomers yield much more intense ion currents with the alkali metals than do others. These findings should contribute to a wider use of laser desorption, including selective examination of mixtures for particular types of compounds, as well as detailed structural studies on individual substances." @default.
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• W1993777202 date "1985-04-01" @default.
• W1993777202 modified "2023-09-25" @default.
• W1993777202 title "Matrix enhanced laser desorption in mass spectrometry and tandem mass spectrometry" @default.
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• W1993777202 doi "https://doi.org/10.1002/bms.1200120404" @default.
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