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- W1993801974 abstract "The topotactic oxidation of the bronze KxTiO2 (x close to 0.25), with a hollandite structure, leads to lower x values. By complete oxidation of the parent bronze a new form of titanium dioxide TiO2(H) is obtained. Its structure is the iono-covalent framework of hollandite. By heating above 410°C, TiO2(H) transforms into anatase. Starting from a single crystal of the precursor bronze it is possible to obtain a partly disintercalated single-crystal product. In this way, K0.06TiO2 has been prepared and its structure determined." @default.
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- W1993801974 date "1989-07-01" @default.
- W1993801974 modified "2023-10-18" @default.
- W1993801974 title "New hollandite oxides: TiO2(H) and K0.06TiO2" @default.
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- W1993801974 doi "https://doi.org/10.1016/0022-4596(89)90204-1" @default.
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