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• W1993816175 abstract "An electric double-layer capacitor (EDLC) has high potential for storing electrical energy at a high power density. It was reported that a narrow nanopore system provides higher performance of EDLCs. In such a system, propylene carbonate (PC) is generally used as a solvent in EDLCs. Hence, the structure of PC in the slit-shaped carbon nanopores should be investigated to reveal the EDLC mechanism. In this paper, grand canonical Monte Carlo simulation of PC adsorbed in nanopores was performed to elucidate molecular-level understanding of the influence of PC on the EDLC performance. PC molecules have a highly ordered structure and longer intermolecular distances in nanopores of a pore width less than 0.7 nm. Thus, the highly ordered and low-density structure formation of the adsorbed PC molecules in narrow nanopores provides a permeation path for electrolytes through nanopores, indicating high-performance EDLCs." @default.
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• W1993816175 date "2011-10-26" @default.
• W1993816175 modified "2023-10-03" @default.
• W1993816175 title "Local Ordered Structure of Propylene Carbonate in Slit-Shaped Carbon Nanopores by GCMC Simulation" @default.
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• W1993816175 doi "https://doi.org/10.5402/2011/708927" @default.
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