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- W1993831308 abstract "Two new compounds [Zn2L(OH)H2O]n (1) and [Cd(HL)]n (2) have been assembled from a semirigid V-shape ligand under hydrothermal conditions. The two compounds were determined by single-crystal X-ray diffraction analyses and further characterized by solid state emission spectra, IR spectra, and thermogravimetric analyses. Single crystal X-ray diffraction analyses show that both of the two compounds crystallize in space group P1¯ and display a three-dimensional (3D) structure with different topologies of fluorite topology for 1 and Au4Ho topology for 2. It is noteworthing that 1 has a novel Zn2 dinuclear unit containing only one bridging oxygen atom between two Zn atoms. Studies of photophysical properties reveal that 1 and 2 present luminescence, which can be ascribed to the emission of intraligand transition." @default.
- W1993831308 created "2016-06-24" @default.
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- W1993831308 date "2013-04-01" @default.
- W1993831308 modified "2023-09-22" @default.
- W1993831308 title "Two new three-dimensional metal–organic frameworks constructed from a semirigid V-shaped ligand with luminescent and topology studies" @default.
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- W1993831308 doi "https://doi.org/10.1016/j.ica.2013.01.015" @default.
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