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- W1993847723 abstract "The reaction of aryl halides with secondary amines in the presence of silylamide base and tri-o-tolyphopshine palladium complexes gives arylamine products. This process provides a convenient method for performing these hetero-cross coupling reactions without the necessity for forming tin amides and disposing of tin halides. This reaction follows from a mechanistic analysis of the coupling reaction with tin amides and occurs as a result of the cleavage of palladium aryl halide dimers with secondary amines." @default.
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- W1993847723 date "1995-05-01" @default.
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- W1993847723 title "Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents" @default.
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- W1993847723 doi "https://doi.org/10.1016/0040-4039(95)00605-c" @default.
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