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- W1993865732 abstract "In the bulk noble metals there is considerable tension or opposition between two sets of forces: a pairwise repulsion due to the full d shells, and a multi-atom electron gas attraction from the sp electrons. Ideal, Gibbs surfaces tend to be unstable because the two forces react differently to the surface cut, upsetting their mutual equilibrium. In particular the flow of the mobile sp electrons can lead to expansive or contractive stresses, strongly dependent upon the local geometry and also sensitive to electron donors/acceptors. These stresses may in turn result in small surface relaxations or more major changes of the surface structure. This type of analysis is applied in detail to gold surfaces, reconciling apparently inconsistent experimental data. Wider implications are also mentioned." @default.
- W1993865732 created "2016-06-24" @default.
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- W1993865732 date "1986-01-01" @default.
- W1993865732 modified "2023-09-27" @default.
- W1993865732 title "Competition between pairwise and multi-atom forces at noble metal surfaces" @default.
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- W1993865732 doi "https://doi.org/10.1016/0039-6028(86)90664-3" @default.
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