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- W1993868923 abstract "The accidental near-degeneracies of the no (oxygen nonbonding) and π2 (antisymmetric pi) MO's of formamide and formic acid have been investigated using photoelectron spectroscopy and SCF calculations of the successive ionization potentials. It is concluded that ionization from no preceeds that from π2 in both of these compounds, but that the reverse order obtains in M-methylformamide and N,N-dimethylformamide. The close correspondence between the profiles of the no and π2 photoelectron bands and the Rydberg band profiles observed optically is used in making a more detailed assignment of the optical bands. All ionization potentials below 20 eV are reported for each of the four compounds." @default.
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- W1993868923 date "1969-05-01" @default.
- W1993868923 modified "2023-10-09" @default.
- W1993868923 title "Photoelectron spectroscopy of simple amides and carboxylic acids" @default.
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- W1993868923 doi "https://doi.org/10.1016/0009-2614(69)80233-2" @default.
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