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- W1993869897 abstract "The structure of the title compound has been determined by X-ray diffraction at 190 K. The complex has an all trans configuration with an elongated tetragonally distorted octahedral CuO6 chromophore. The elongated axis corresponding to the trans-Cu–O(ether) bonds. The ligand molecules are bidentate via the carboxyl and the 3-ether O atoms; the 6-ether O atoms are not coordinated and are remote from the Cu centres. The bond lengths to the Cu centres are Cu–O(ether) 2.355 Å, Cu–O(Carboxyl) 1.933 Å and Cu–OH2 1.995 Å. The EPR spectrum of both the powder and frozen solution forms is typical of a rhombic system with a dx2−y21 electronic configuration. There were no significant differences in spectra recorded over the temperature range 77 K to room temperature. These results are discussed in relation to earlier published results on closely related oxa-carboxyl complexes." @default.
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- W1993869897 date "2001-01-01" @default.
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- W1993869897 title "Diaquabis(3,6-dioxaheptanoato)copper(II): crystal structure and EPR characteristics" @default.
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- W1993869897 doi "https://doi.org/10.1016/s0020-1693(00)00365-0" @default.
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