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- W1993871804 abstract "Block copolymers can adopt a wide range of morphologies in dilute aqueous solution. There is a significant amount of interest in the use of block copolymer vesicles for a number of applications. We show that a series of oligo(valine) and oligo(phenylalanine) peptides coupled to a methacrylic group can be prepared by conventional peptide coupling techniques. These can be successfully polymerized by atom transfer radical polymerization (ATRP) in hexafluoroisopropanol (HFIP) giving access to poly(ethylene oxide)- b-poly(side-chain peptides). Many of these polymers self-assemble to form vesicles using an organic to aqueous solvent exchange. One example with a divaline hydrophobic block gives a mixture of toroids and vesicles. Circular dichroism demonstrates that secondary structuring is observed in the hydrophobic region of the vesicle walls for the valine side-chain containing polymers." @default.
- W1993871804 created "2016-06-24" @default.
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- W1993871804 date "2008-09-27" @default.
- W1993871804 modified "2023-09-23" @default.
- W1993871804 title "Vesicles from Peptidic Side-Chain Polymers Synthesized by Atom Transfer Radical Polymerization" @default.
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- W1993871804 doi "https://doi.org/10.1021/bm8006693" @default.
- W1993871804 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18821797" @default.
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