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- W1993874769 abstract "Abstract Of significant interest in the field of relaxation mechanisms in polymer systems is the possible existence of a spatial heterogeneity existing in an otherwise single phase homogenous polymer material. Here, frequency dependent dielectric and mechanical measurements along with DSC measurements show that as early as 5% conversion during cure of a styrene–dimethacrylate systems, two distinctly different α -relaxation regions exist along with two T g is in the DSC spectra. The heterogeneity persists as the cure advances. The breadth of each relaxation increases and results in an extremely broad relaxation spectrum and T g transition near cure completion. This result also provides an additional example demonstrating that the existence of two T g is does not by itself indicate phase separation." @default.
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- W1993874769 date "2006-11-01" @default.
- W1993874769 modified "2023-10-18" @default.
- W1993874769 title "Dielectric, dynamic mechanical and DSC evidence for a spatial and dynamic heterogeneity in a single phase polymer system" @default.
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- W1993874769 doi "https://doi.org/10.1016/j.jnoncrysol.2006.01.133" @default.
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