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- W1993886360 abstract "The kinetics of dedeuteration under the action of potassium amide in liquid ammonia in a series of sulfides with open chain, open chain-alicyclic and open chain-aromatic substituents and a number of their oxygen analogs have been determined to investigate the electronic effect of 3d orbital conjugation in divalent sulfur compounds. The conjugation of the 3d orbitals of sulfur has been studied (1) with the adjacent, negatively charged carbon electrons of the intermediate carbanion; (2) with a pair of unshared electrons of the substituent (OMe, N(Me2); via the benzene ring) in the ground state of the sulfide molecule; (3) with the charge (via the benzene ring) in the intermediate anion formed in the exchange reaction. (4) In addition hyperconjugation of the type -SCH2H+ has been investigated." @default.
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- W1993886360 date "1969-01-01" @default.
- W1993886360 modified "2023-09-26" @default.
- W1993886360 title "Deuteroexchange study of 3d orbital conjugation in organic sulfides" @default.
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- W1993886360 doi "https://doi.org/10.1016/0040-4020(69)80018-9" @default.
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