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- W1993899768 abstract "The size, shape, and connectivity of cavities in the crystals of syndiotactic polystyrene were investigated by molecular dynamics simulation. Cluster analysis of the free volume in the crystals clearly reveals the cavity structures: large individual holes are in an orderly manner connected by narrow channels. We call such a cavity structure a ‘molecular cavity’. The diffusion behavior and solubility of gases in the molecular cavity were also simulated. The extremely high solubility of a larger gas and the controllable diffusion path in the narrow channels proved the applicability of the concept of the molecular cavity to high performance separation membranes." @default.
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- W1993899768 date "2003-05-01" @default.
- W1993899768 modified "2023-09-23" @default.
- W1993899768 title "Nanoscale molecular cavity in crystalline polymer membranes studied by molecular dynamics simulation" @default.
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- W1993899768 doi "https://doi.org/10.1016/s0032-3861(03)00214-3" @default.
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