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• W1993949731 abstract "An analysis of the enthalpies of mixing, obtained experimentally at 298.15 K and at atmospheric pressure, of sixteen binary systems formed by four ethyl esters, from formate to butanoate, and four 1-chloroalkanes, from pentane to octane, is presented in this work. The experimental values of hE have been examined by a version of the UNIFAC model, as modified by Skjold-Jorgensen, as well as by the molecular group contribution model of Nitta. In both cases, the interaction parameters necessary for the prediction of the hE of the binary systems ester/1-chloroalkanes are determined, mainly the parameters involving the groups HCOO, COOC or COO, CH3 or CH2 and Cl. The predictions of hE, carried out both with the modified UNIFAC model and with the molecular model of Nitta, are similar. Thus, for the system ethyl formate+ 1-chloroalkanes, errors are lower than 6% with the UNIFAC model and less than 8% with that of Nitta. For the remaining systems, the errors increase as the chain length of the ester increases or as the hE decrease." @default.
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• W1993949731 date "1988-12-01" @default.
• W1993949731 modified "2023-09-29" @default.
• W1993949731 title "Analysis of excess enthalpies of ester+ 1-chloroalkanes with two group contribution models: primary parameters" @default.
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• W1993949731 doi "https://doi.org/10.1016/0378-3812(88)87011-0" @default.
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