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- W1993971029 abstract "The theory of temperature-dependent topological constraints has been used to successfully explain the compositional dependence of glass properties for oxide and non-oxide compositions. However, even though the predictions are qualitatively accurate, not all quantitative predictions are as precise. Here, we report on the applications of this theoretical framework to available data for binary phosphate and silver metaphosphate – silver halide glasses. We find that some compositions are overconstrained and some are underconstrained relative to the predicted values. We suggest that the origin of this difference is due to the presence of medium-range constraints such as sterical hindrance which is dependent on packing density and chain length." @default.
- W1993971029 created "2016-06-24" @default.
- W1993971029 creator A5021241484 @default.
- W1993971029 creator A5089740992 @default.
- W1993971029 date "2013-06-27" @default.
- W1993971029 modified "2023-10-15" @default.
- W1993971029 title "Medium-range topological constraints in binary phosphate glasses" @default.
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- W1993971029 doi "https://doi.org/10.1063/1.4810868" @default.
- W1993971029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23822256" @default.
- W1993971029 hasPublicationYear "2013" @default.
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