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- W1993978324 abstract "Single-site organometallic catalysts supported on solid inorganic or organic substrates are making an important contribution to heterogeneous catalysis. Early and late transition metal single-site catalysts have changed the polyolefin manufacturing industry and research with their ability to produce polymers with unique properties. Moreover, several of these catalysts have been commercialized on a large scale. Their heterogenization for slurry or gas phase olefin polymerization is important to produce polyolefin as beads and to avoid reactor fouling. The large majority of supports currently used in industry are inorganic materials (SiO2, Al2O3, MgCl2), with silica being the most important. Single-site supported catalysts are most commonly prepared by molecular-level anchoring/chemisorption, in which a molecular precursor undergoes reaction with the surface while maintaining most of the ligand sphere of the parent molecule. Chemisorption of discrete organometallic complexes on solid supports yields catalysts with well-defined active sites, greater thermal stability than the homogeneous analogues, and decreased reactor fouling versus the homogeneous analogues. This review presents a detailed account of the synthesis, characterization and polymerization properties of single-site catalysts supported on metal oxides and metal sulfated oxides, primarily carried out at Northwestern University. Early and late transition metal single-site catalysts supported on inorganic surfaces have changed the polyolefin research and production with their unique ability to produce polymeric materials with unique architectures. This review presents a detailed account of the synthesis, characterization, and polymerization properties of single-site catalysts supported on metal oxide surfaces." @default.
- W1993978324 created "2016-06-24" @default.
- W1993978324 creator A5000731301 @default.
- W1993978324 creator A5010105358 @default.
- W1993978324 creator A5054572356 @default.
- W1993978324 date "2014-11-18" @default.
- W1993978324 modified "2023-10-10" @default.
- W1993978324 title "Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins" @default.
- W1993978324 cites W1502171686 @default.
- W1993978324 cites W1614960225 @default.
- W1993978324 cites W1644641295 @default.
- W1993978324 cites W1793873404 @default.
- W1993978324 cites W18607393 @default.
- W1993978324 cites W1969836553 @default.
- W1993978324 cites W1970178844 @default.
- W1993978324 cites W1970897185 @default.
- W1993978324 cites W1975989632 @default.
- W1993978324 cites W1977168693 @default.
- W1993978324 cites W1977635666 @default.
- W1993978324 cites W1978512906 @default.
- W1993978324 cites W1979029568 @default.
- W1993978324 cites W1979058149 @default.
- W1993978324 cites W1981882062 @default.
- W1993978324 cites W1986119632 @default.
- W1993978324 cites W1987449135 @default.
- W1993978324 cites W1987901467 @default.
- W1993978324 cites W1989308060 @default.
- W1993978324 cites W1990780552 @default.
- W1993978324 cites W1993610879 @default.
- W1993978324 cites W1995868076 @default.
- W1993978324 cites W1996099267 @default.
- W1993978324 cites W2000067959 @default.
- W1993978324 cites W2000343675 @default.
- W1993978324 cites W2001378060 @default.
- W1993978324 cites W2002788226 @default.
- W1993978324 cites W2004086537 @default.
- W1993978324 cites W2004182290 @default.
- W1993978324 cites W2005080232 @default.
- W1993978324 cites W2005594390 @default.
- W1993978324 cites W2006792934 @default.
- W1993978324 cites W2007210502 @default.
- W1993978324 cites W2007767017 @default.
- W1993978324 cites W2008783235 @default.
- W1993978324 cites W2009726182 @default.
- W1993978324 cites W2012591289 @default.
- W1993978324 cites W2013464543 @default.
- W1993978324 cites W2014020522 @default.
- W1993978324 cites W2014033694 @default.
- W1993978324 cites W2014206076 @default.
- W1993978324 cites W2014361844 @default.
- W1993978324 cites W2016689740 @default.
- W1993978324 cites W2017032157 @default.
- W1993978324 cites W2017736005 @default.
- W1993978324 cites W2018353982 @default.
- W1993978324 cites W2019130521 @default.
- W1993978324 cites W2019972363 @default.
- W1993978324 cites W2020226922 @default.
- W1993978324 cites W2020459210 @default.
- W1993978324 cites W2021728033 @default.
- W1993978324 cites W2022244698 @default.
- W1993978324 cites W2022985003 @default.
- W1993978324 cites W2023692017 @default.
- W1993978324 cites W2030908665 @default.
- W1993978324 cites W2037558221 @default.
- W1993978324 cites W2038493059 @default.
- W1993978324 cites W2039006756 @default.
- W1993978324 cites W2039410044 @default.
- W1993978324 cites W2039450143 @default.
- W1993978324 cites W2040086753 @default.
- W1993978324 cites W2041647217 @default.
- W1993978324 cites W2042044087 @default.
- W1993978324 cites W2044874220 @default.
- W1993978324 cites W2045490147 @default.
- W1993978324 cites W2048574139 @default.
- W1993978324 cites W2048796469 @default.
- W1993978324 cites W2049543666 @default.
- W1993978324 cites W2051166993 @default.
- W1993978324 cites W2052378973 @default.
- W1993978324 cites W2053286705 @default.
- W1993978324 cites W2053752697 @default.
- W1993978324 cites W2055709121 @default.
- W1993978324 cites W2056685742 @default.
- W1993978324 cites W2058761984 @default.
- W1993978324 cites W2061221675 @default.
- W1993978324 cites W2061566121 @default.
- W1993978324 cites W2062568471 @default.
- W1993978324 cites W2066160463 @default.
- W1993978324 cites W2066985393 @default.
- W1993978324 cites W2068484608 @default.
- W1993978324 cites W2076471799 @default.
- W1993978324 cites W2080606445 @default.
- W1993978324 cites W2081595444 @default.
- W1993978324 cites W2081803497 @default.
- W1993978324 cites W2081891232 @default.
- W1993978324 cites W2083924613 @default.
- W1993978324 cites W2084311144 @default.
- W1993978324 cites W2085508332 @default.
- W1993978324 cites W2089908251 @default.