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- W1993994536 abstract "The effect of some α-amino acids and their esters on the stability of the binary pyrene/heptakis-(6-amino-6-deoxy)-β-cyclodextrin (py/am-β-CD) complex has been studied by means of fluorescence spectroscopy at two pH values (8.0 and 9.0). The binary complex was generally stabilized by adding the ternary agent at pH 8.0. A more varied substrate effect is observed at pH 9.0 where am-β-CD is present in the uncharged form. The conditional constant (β2) values determined by l/d α-amino acids show that the binary complex is a suitable receptor for chiral recognition. The enantiomer selectivity values obtained, ranging from 1.2 up to 7.4, are generally higher than those reported for α-amino acids and their derivatives by modified cyclodextrins." @default.
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- W1993994536 date "2002-08-01" @default.
- W1993994536 modified "2023-09-25" @default.
- W1993994536 title "The binary pyrene/heptakis-(6-amino-6-deoxy)-β-cyclodextrin complex: a suitable chiral discriminator. Spectrofluorimetric study of the effect of some α-amino acids and esters on the stability of the binary complex" @default.
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- W1993994536 doi "https://doi.org/10.1016/s0957-4166(02)00418-4" @default.
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