FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1993998445> ?p ?o ?g. }

• W1993998445 endingPage "254" @default.
• W1993998445 startingPage "245" @default.
• W1993998445 abstract "The phosphorescence spectrum of benzene is particularly rich in vibronic structure and provides the best-known example of a spectrum of electronic transitions that by symmetry is both spin and orbital forbidden. Such transitions, only allowed through the coupling of nuclear and electronic motions, are notoriously difficult to analyze both on theoretical and experimental grounds. We investigate the vibronically induced phosphorescence by means of multi-configuration quadratic response theory calculations and explore vibronic intensities, polarization directions, transition moments for benzene phosphorescence and the radiative lifetime of triplet benzene. We find that the radiative decay of the 3B1u state takes place predominantly through vibronic coupling among the e2g CC stretching modes ν8=1601 cm−1 and ν9=1178 cm−1, with a close to complete out-of-plane polarization. The calculations predict relative intensities of different vibronic bands in good agreement with experiment. The oscillator strength for the 3B1u←1A1g absorption is predicted to 0.74×10−10, to be compared with the experimental value of ≈10−10. The computed averaged radiative lifetime falls in the interval of 22 to 96 seconds, depending on the quality of the basis set, with the best prediction being 64 seconds." @default.
• W1993998445 created "2016-06-24" @default.
• W1993998445 creator A5000726017 @default.
• W1993998445 creator A5053665869 @default.
• W1993998445 creator A5078745548 @default.
• W1993998445 creator A5079207273 @default.
• W1993998445 date "1993-09-01" @default.
• W1993998445 modified "2023-09-27" @default.
• W1993998445 title "The vibronically induced phosphorescence in benzene" @default.
• W1993998445 cites W1485155141 @default.
• W1993998445 cites W1520822480 @default.
• W1993998445 cites W1968756520 @default.
• W1993998445 cites W1981578015 @default.
• W1993998445 cites W1995830592 @default.
• W1993998445 cites W2000478760 @default.
• W1993998445 cites W2016792744 @default.
• W1993998445 cites W2020547692 @default.
• W1993998445 cites W2028788575 @default.
• W1993998445 cites W2041342117 @default.
• W1993998445 cites W2042288705 @default.
• W1993998445 cites W2043527527 @default.
• W1993998445 cites W2045833401 @default.
• W1993998445 cites W2050039205 @default.
• W1993998445 cites W2052835348 @default.
• W1993998445 cites W2055007845 @default.
• W1993998445 cites W2057750183 @default.
• W1993998445 cites W2062340785 @default.
• W1993998445 cites W2067381437 @default.
• W1993998445 cites W2069409865 @default.
• W1993998445 cites W2070331428 @default.
• W1993998445 cites W2071072703 @default.
• W1993998445 cites W2074084153 @default.
• W1993998445 cites W2076198299 @default.
• W1993998445 cites W2083441840 @default.
• W1993998445 cites W2084686289 @default.
• W1993998445 cites W2087039044 @default.
• W1993998445 cites W2140815460 @default.
• W1993998445 cites W2141798332 @default.
• W1993998445 cites W2144156709 @default.
• W1993998445 cites W2153620923 @default.
• W1993998445 cites W2156354763 @default.
• W1993998445 cites W2158469063 @default.
• W1993998445 cites W4252598364 @default.
• W1993998445 doi "https://doi.org/10.1016/0301-0104(93)85153-y" @default.
• W1993998445 hasPublicationYear "1993" @default.
• W1993998445 type Work @default.
• W1993998445 sameAs 1993998445 @default.
• W1993998445 citedByCount "46" @default.
• W1993998445 countsByYear W19939984452012 @default.
• W1993998445 countsByYear W19939984452013 @default.
• W1993998445 countsByYear W19939984452014 @default.
• W1993998445 countsByYear W19939984452015 @default.
• W1993998445 countsByYear W19939984452016 @default.
• W1993998445 countsByYear W19939984452017 @default.
• W1993998445 countsByYear W19939984452019 @default.
• W1993998445 countsByYear W19939984452021 @default.
• W1993998445 countsByYear W19939984452022 @default.
• W1993998445 countsByYear W19939984452023 @default.
• W1993998445 crossrefType "journal-article" @default.
• W1993998445 hasAuthorship W1993998445A5000726017 @default.
• W1993998445 hasAuthorship W1993998445A5053665869 @default.
• W1993998445 hasAuthorship W1993998445A5078745548 @default.
• W1993998445 hasAuthorship W1993998445A5079207273 @default.
• W1993998445 hasConcept C121332964 @default.
• W1993998445 hasConcept C147789679 @default.
• W1993998445 hasConcept C160172526 @default.
• W1993998445 hasConcept C178790620 @default.
• W1993998445 hasConcept C181817918 @default.
• W1993998445 hasConcept C182498248 @default.
• W1993998445 hasConcept C184779094 @default.
• W1993998445 hasConcept C185592680 @default.
• W1993998445 hasConcept C198990423 @default.
• W1993998445 hasConcept C205049153 @default.
• W1993998445 hasConcept C2777691172 @default.
• W1993998445 hasConcept C32909587 @default.
• W1993998445 hasConcept C62520636 @default.
• W1993998445 hasConcept C74902906 @default.
• W1993998445 hasConcept C91881484 @default.
• W1993998445 hasConceptScore W1993998445C121332964 @default.
• W1993998445 hasConceptScore W1993998445C147789679 @default.
• W1993998445 hasConceptScore W1993998445C160172526 @default.
• W1993998445 hasConceptScore W1993998445C178790620 @default.
• W1993998445 hasConceptScore W1993998445C181817918 @default.
• W1993998445 hasConceptScore W1993998445C182498248 @default.
• W1993998445 hasConceptScore W1993998445C184779094 @default.
• W1993998445 hasConceptScore W1993998445C185592680 @default.
• W1993998445 hasConceptScore W1993998445C198990423 @default.
• W1993998445 hasConceptScore W1993998445C205049153 @default.
• W1993998445 hasConceptScore W1993998445C2777691172 @default.
• W1993998445 hasConceptScore W1993998445C32909587 @default.
• W1993998445 hasConceptScore W1993998445C62520636 @default.
• W1993998445 hasConceptScore W1993998445C74902906 @default.
• W1993998445 hasConceptScore W1993998445C91881484 @default.
• W1993998445 hasIssue "2-3" @default.
• W1993998445 hasLocation W19939984451 @default.
• W1993998445 hasOpenAccess W1993998445 @default.
• W1993998445 hasPrimaryLocation W19939984451 @default.
• W1993998445 hasRelatedWork W1964605513 @default.

• next