FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994009899> ?p ?o ?g. }

• W1994009899 endingPage "81" @default.
• W1994009899 startingPage "67" @default.
• W1994009899 abstract "The present work describes the development and validation of a sensitive method for the determination of traces of diverse groups of pharmaceuticals and endocrine disruptors in surface water. Thirty-seven substances have been selected, including 10 pesticides, 6 hormonal steroids and assimilates, 12 pharmaceuticals, 5 alkylphenols, 1 chlorophenol and 3 other well-known human contaminants, 1 UV filter and 2 plasticisers. An automated online solid-phase extraction (SPE) is directly coupled to liquid chromatography–tandem mass spectrometry. Different SPE columns have been tested, and the injection volume has been optimised. The developed analytical methodology is based on the direct injection of 2.5 mL of water sample acidified at pH 1.6 on an Oasis HLB loading column (20 × 2.1 mm) with 5-µm particles. Then, the chromatographic separation is achieved on a Kinetex XB C18 (100 × 2.1 mm; 1.7 µm) column, and the quantification is realised in multiple-reaction monitoring mode. The online SPE step warrants minimal sample handling, low solvent consumption, high sample throughput, saving time and costs. This method allows the quantification of the target analytes in the lower ng/L concentration range, with limits of quantification (LQs) between 100 pg/L and 10 ng/L, 26 compounds having LQ lower than 1 ng/L. The monitoring of two selected MS/MS transitions for each compound allows the reliable confirmation of positive findings even at the LQ level. The developed and validated methodology has been applied to the analysis of various real samples from two French rivers. Twelve target compounds have been detected in the environmental samples, and the major pollutants are pharmaceuticals usually used by humans (paracetamol, carbamazepine, oxazepam, ketoprofen, trimethoprim). The pesticides atrazine and carbendazim have been ubiquitously detected in real samples too. Metronidazole, sulfamethoxazole and diuron were also frequently quantified in the water samples." @default.
• W1994009899 created "2016-06-24" @default.
• W1994009899 creator A5015102045 @default.
• W1994009899 creator A5026653041 @default.
• W1994009899 creator A5037264510 @default.
• W1994009899 creator A5040195704 @default.
• W1994009899 creator A5048222691 @default.
• W1994009899 creator A5070085945 @default.
• W1994009899 date "2014-12-20" @default.
• W1994009899 modified "2023-10-14" @default.
• W1994009899 title "Multiresidue fully automated online SPE-HPLC-MS/MS method for the quantification of endocrine-disrupting and pharmaceutical compounds at trace level in surface water" @default.
• W1994009899 cites W1966552710 @default.
• W1994009899 cites W1968700347 @default.
• W1994009899 cites W1970316098 @default.
• W1994009899 cites W1974661969 @default.
• W1994009899 cites W1975536182 @default.
• W1994009899 cites W1978003950 @default.
• W1994009899 cites W1980000265 @default.
• W1994009899 cites W1985716793 @default.
• W1994009899 cites W1993986875 @default.
• W1994009899 cites W1994568028 @default.
• W1994009899 cites W1995498600 @default.
• W1994009899 cites W1997527498 @default.
• W1994009899 cites W1998207372 @default.
• W1994009899 cites W2013031384 @default.
• W1994009899 cites W2015819599 @default.
• W1994009899 cites W2023704290 @default.
• W1994009899 cites W2028681215 @default.
• W1994009899 cites W2028882927 @default.
• W1994009899 cites W2033146579 @default.
• W1994009899 cites W2037766564 @default.
• W1994009899 cites W2040282810 @default.
• W1994009899 cites W2045247511 @default.
• W1994009899 cites W2045753556 @default.
• W1994009899 cites W2047744737 @default.
• W1994009899 cites W2048235558 @default.
• W1994009899 cites W2053296928 @default.
• W1994009899 cites W2055523389 @default.
• W1994009899 cites W2059201410 @default.
• W1994009899 cites W2059822016 @default.
• W1994009899 cites W2059855535 @default.
• W1994009899 cites W2060638574 @default.
• W1994009899 cites W2064572212 @default.
• W1994009899 cites W2065298420 @default.
• W1994009899 cites W2067442115 @default.
• W1994009899 cites W2074773878 @default.
• W1994009899 cites W2074807955 @default.
• W1994009899 cites W2080373067 @default.
• W1994009899 cites W2082643813 @default.
• W1994009899 cites W2083159992 @default.
• W1994009899 cites W2089780923 @default.
• W1994009899 cites W2093643731 @default.
• W1994009899 cites W2128890559 @default.
• W1994009899 cites W2141919009 @default.
• W1994009899 cites W2146748959 @default.
• W1994009899 cites W2149470993 @default.
• W1994009899 cites W2169412126 @default.
• W1994009899 cites W2484214574 @default.
• W1994009899 doi "https://doi.org/10.1080/03067319.2014.983494" @default.
• W1994009899 hasPublicationYear "2014" @default.
• W1994009899 type Work @default.
• W1994009899 sameAs 1994009899 @default.
• W1994009899 citedByCount "32" @default.
• W1994009899 countsByYear W19940098992015 @default.
• W1994009899 countsByYear W19940098992016 @default.
• W1994009899 countsByYear W19940098992017 @default.
• W1994009899 countsByYear W19940098992018 @default.
• W1994009899 countsByYear W19940098992020 @default.
• W1994009899 countsByYear W19940098992021 @default.
• W1994009899 countsByYear W19940098992022 @default.
• W1994009899 countsByYear W19940098992023 @default.
• W1994009899 crossrefType "journal-article" @default.
• W1994009899 hasAuthorship W1994009899A5015102045 @default.
• W1994009899 hasAuthorship W1994009899A5026653041 @default.
• W1994009899 hasAuthorship W1994009899A5037264510 @default.
• W1994009899 hasAuthorship W1994009899A5040195704 @default.
• W1994009899 hasAuthorship W1994009899A5048222691 @default.
• W1994009899 hasAuthorship W1994009899A5070085945 @default.
• W1994009899 hasConcept C10390740 @default.
• W1994009899 hasConcept C112570922 @default.
• W1994009899 hasConcept C119128265 @default.
• W1994009899 hasConcept C162356407 @default.
• W1994009899 hasConcept C178790620 @default.
• W1994009899 hasConcept C179998833 @default.
• W1994009899 hasConcept C185592680 @default.
• W1994009899 hasConcept C18903297 @default.
• W1994009899 hasConcept C2778576202 @default.
• W1994009899 hasConcept C2780471494 @default.
• W1994009899 hasConcept C43617362 @default.
• W1994009899 hasConcept C4725764 @default.
• W1994009899 hasConcept C81426234 @default.
• W1994009899 hasConcept C86803240 @default.
• W1994009899 hasConceptScore W1994009899C10390740 @default.
• W1994009899 hasConceptScore W1994009899C112570922 @default.
• W1994009899 hasConceptScore W1994009899C119128265 @default.
• W1994009899 hasConceptScore W1994009899C162356407 @default.
• W1994009899 hasConceptScore W1994009899C178790620 @default.
• W1994009899 hasConceptScore W1994009899C179998833 @default.

• next