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- W1994014781 abstract "The presence of anionic cosolutes often influences anion adsorption on soil mineral surfaces. The possible effect of common solutes, such as CO 3 species, on the adsorption of other anions on metal (hydr)oxides is poorly understood. Accordingly, we determined the effect of CO 3 , formate, acetate, oxalate, and citrate on the adsorption of SO 4 and SeO 4 on Al oxide. Carbonate markedly promotes the adsorption of SO 4 and SeO 4 between pH 6 and 8. The maximum effect occurs at relatively low CO 3 concentrations (0.3 m M ) and the promotive effect decreases with further increase in CO 3 adsorption. Formate and acetate also promote adsorption of SO 4 and SeO 4 , while oxalate and citrate have a competitive effect, especially at lower pH values. Based on existing Fourier transformed infrared (FTIR) spectroscopic data and new electrophoretic mobility data, CO 3 may promote the adsorption of other oxyanions by forming extra reactive protonated sites that exist with the adsorbed CO 3 Acetate and formate presumably interact through the same mechanism. This promotive mechanism was ineffective in the case of adsorption of a high affinity anion such as PO 4 Finally, the adsorptive properties of Al oxide, as we know it from simple model systems, can significantly be altered in soils, where CO 3 and organic anions are ubiquitous solutes. For example, the adsorption maximum of SO 4 > SeO 4 became in the presence of CO 3" @default.
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- W1994014781 date "2000-05-01" @default.
- W1994014781 modified "2023-09-27" @default.
- W1994014781 title "Interaction of Carbonate and Organic Anions with Sulfate and Selenate Adsorption on an Aluminum Oxide" @default.
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- W1994014781 doi "https://doi.org/10.2136/sssaj2000.643898x" @default.
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