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- W1994047190 abstract "The cyclen based pyridine complexes 1Ln–3Ln (Ln = La(III) and Eu(III)) were synthesised as metallo-ribonuclease mimics and their ability to hydrolytically cleave the phosphodiester of HPNP at 37 °C was investigated using UV–vis spectroscopy, whereas the binding of the substrate was evaluated using 31P NMR and Eu(III)-luminescent measurements. In contrast 2La gave rise to fast pH dependent hydrolysis of HPNP, with maximum efficiency at ca. pH 8.2, and with a half-lifetime of ∼1 h, the 1Ln and 3Ln complexes were found to be inactive, emphasizing the importance of the nature of the pyridine isomer as a cofactor in the hydrolytic process." @default.
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- W1994047190 date "2005-05-01" @default.
- W1994047190 modified "2023-10-12" @default.
- W1994047190 title "Cyclen based lanthanide ion ribonuclease mimics: the effect of pyridine cofactors upon phosphodiester HPNP hydrolysis" @default.
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- W1994047190 doi "https://doi.org/10.1016/j.tetlet.2005.03.150" @default.
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