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- W1994060490 abstract "The taxane family is one of the most challenging synthetic targets due to their unique carbon skeleton coupled with the highly potent anticancer activities of a congener, taxol. We have developed a powerful methodology based on Lewis acid mediated direct eight-membered-ring cyclization for taxane B ring that offers a general route for natural taxane synthesis. The methodology provides simultaneous solution for the following three of the most difficult problems for taxane synthesis.1) construction of the highly strained eight-membered B ring2) stereoselective installation of the C-9 and C-10 oxygen functionalities3) stereocontrol of the endo conformation." @default.
- W1994060490 created "2016-06-24" @default.
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- W1994060490 date "2010-08-21" @default.
- W1994060490 modified "2023-09-25" @default.
- W1994060490 title "ChemInform Abstract: Synthetic Studies on Taxane Diterpenes" @default.
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- W1994060490 doi "https://doi.org/10.1002/chin.199247318" @default.
- W1994060490 hasPublicationYear "2010" @default.
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