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- W1994062526 abstract "Abstract The 4-substituted silacyclohex-3-enes (3) prepared from the vinyl triflate (9) derived from 1,1-dimethyl-1-silacyclohexan-4-one (1) and higher-order organocuprates provides a versatile template for the construction of non-racemic 3-methyl-4-penten-1-ol (6). Through asymmetric hydroboration, 3 affords the requisite β-hydroxysilane (4) with the ideal geometry to undergo elimination to the chiral acyclic silane (5) which is oxidatively converted to 6." @default.
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- W1994062526 date "1998-12-01" @default.
- W1994062526 modified "2023-10-03" @default.
- W1994062526 title "Silacycles as templates for acyclic diastereoselection" @default.
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- W1994062526 doi "https://doi.org/10.1016/s0040-4039(98)02200-x" @default.
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