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• W1994084562 abstract "The photocatalytic reduction of CO2 by water vapor to produce light hydrocarbons was studied over a series of catalysts consisting of variable loading of Ti incorporated in TUD-1 mesoporous silica, either modified by ZnO nanoparticles or isolated Cr-sites. Unexpectedly, the performance of ZnO-Ti-TUD-1 and Cr-Ti-TUD-1 was inferior to the parent Ti-TUD-1. An explanation can be found in experiments on the photocatalytic degradation of a mixture of hydrocarbons (i.e., CH4, C2H4, C2H6, C3H6, and C3H8) under the same illumination conditions. Ti-TUD-1 exhibits the poorest activity in hydrocarbon degradation, while ZnO-Ti-TUD-1 and Cr-Ti-TUD-1 showed very significant degradation rates. This study clearly demonstrates the importance of evaluating hydrocarbon conversion over photocatalysts active in converting CO2 to hydrocarbons (in batch reactors)." @default.
• W1994084562 created "2016-06-24" @default.
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• W1994084562 date "2013-12-30" @default.
• W1994084562 modified "2023-10-16" @default.
• W1994084562 title "Strategies to Design Efficient Silica-Supported Photocatalysts for Reduction of CO₂" @default.
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• W1994084562 doi "https://doi.org/10.1021/ja410363v" @default.
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