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- W1994097718 abstract "Condensation of Tp‘(CO)2M⋮CCl [1a, M = Mo; 1b, W; Tp‘ = HB(3,5-Me2HC3N2)3] with the arsaalkene Me3SiAsC(NMe2)2 afforded the novel arsaalkenyl carbyne complexes Tp‘(CO)2M⋮C−AsC(NMe2)2 (2a) (M = Mo) and 2b (M = W). Methylation of 2a and 2b occurred at the arsenic atom to give the complexes [Tp‘(CO)2M⋮CAs(Me)C(NMe2)2](SO3CF3) 3a (M = Mo) and 3b (M = W). Compounds 2a,b and 3a,b have been characterized by IR and 1H and 13C NMR spectroscopy. In addition, the molecular structure of 2b has been determined by a single-crystal X-ray structural analysis." @default.
- W1994097718 created "2016-06-24" @default.
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- W1994097718 date "1999-10-01" @default.
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- W1994097718 title "Transition-Metal-Substituted Arsaalkenes. 7.<sup>1</sup> Coupling of Transition Metal Carbynes with a Methylene Arsane Moiety: Structure of Tp‘(CO)<sub>2</sub>W⋮C−AsC(NMe<sub>2</sub>)<sub>2</sub> [Tp‘ = HB(3,5-Me<sub>2</sub>HC<sub>3</sub>N<sub>2</sub>)<sub>3</sub>]" @default.
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- W1994097718 doi "https://doi.org/10.1021/om990114n" @default.
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