FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994126350> ?p ?o ?g. }

• W1994126350 endingPage "1600" @default.
• W1994126350 startingPage "1593" @default.
• W1994126350 abstract "The compounds [M{C(OMe)Ph}(CO)5](M = Cr or W) react with [Pt(cod)2](cod = cyclo-octa-1,5-diene) to give metal—metal-bonded complexes [(OC)5[graphic omitted]t(cod)]. Ethylene-saturated light petroleum solutions of [Pt(cod)2], treated with 2 mol of tertiary phosphine, react with the mononuclear metal compounds [M{C(OMe)Ph}(CO)5](M = Cr, Mo, or W) and [W{C(OMe)Me}(CO)5] to afford the carbene-bridged dimetal complexes [(OC)5[graphic omitted]t(PR3)2](M = Cr or Mo, PR3= PMe3 or PMe2Ph; M = W, PR3= PMe3) and [(OC)5[graphic omitted]t(PMe3)2]. Phosphorus-31, 1H and 13C n.m.r. studies support the structures proposed, and for [(OC)5[graphic omitted]t(PMe3)2] the structure has been confirmed by a single-crystal X-ray diffraction study. Crystals are triclinic, with space group P and Z= 2 in a unit cell of dimensions a= 9.728(5), b= 16.002(13), c= 9.611(6)Åα= 109.86(6), β= 116,34(4), and γ= 83.77(6)°. The structure has been determined by heavy-atom methods from automated diffractometer data for 2.9 ⩽ 2θ⩽ 50° and refined to R 0.049 (R′ 0.048) for 3 735 independent reflections. A tungsten–platinum bond (2.861 (1)Å] is asymmetrically bridged by a C(OMe)Ph group [C–Pt 2.04(1), C–W 2.48(1)Å]. Reaction of the compounds [(OC)5[graphic omitted]t(PMe3)2](M = Cr or W) with trimethylphosphine gives the complexes [(Me3P)(OC)4[graphic omitted]t(PMe3)2], while the chromium compound with ButNC yields [(ButNC)2(OC)3[graphic omitted]t(CNBut)(PMe3)]. The n.m.r. data for these products are discussed." @default.
• W1994126350 created "2016-06-24" @default.
• W1994126350 creator A5005146711 @default.
• W1994126350 creator A5017943958 @default.
• W1994126350 creator A5073991542 @default.
• W1994126350 creator A5084930331 @default.
• W1994126350 date "1980-01-01" @default.
• W1994126350 modified "2023-10-16" @default.
• W1994126350 title "Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 1. Synthesis of platinum–chromium, –molybdenum, and –tungsten compounds; crystal structure of [(OC)₅W{µ-C(OMe)Ph}Pt(PMe₃)₂]" @default.
• W1994126350 doi "https://doi.org/10.1039/dt9800001593" @default.
• W1994126350 hasPublicationYear "1980" @default.
• W1994126350 type Work @default.
• W1994126350 sameAs 1994126350 @default.
• W1994126350 citedByCount "41" @default.
• W1994126350 countsByYear W19941263502012 @default.
• W1994126350 countsByYear W19941263502017 @default.
• W1994126350 crossrefType "journal-article" @default.
• W1994126350 hasAuthorship W1994126350A5005146711 @default.
• W1994126350 hasAuthorship W1994126350A5017943958 @default.
• W1994126350 hasAuthorship W1994126350A5073991542 @default.
• W1994126350 hasAuthorship W1994126350A5084930331 @default.
• W1994126350 hasConcept C115624301 @default.
• W1994126350 hasConcept C161790260 @default.
• W1994126350 hasConcept C178790620 @default.
• W1994126350 hasConcept C179104552 @default.
• W1994126350 hasConcept C185592680 @default.
• W1994126350 hasConcept C2777164566 @default.
• W1994126350 hasConcept C2777716191 @default.
• W1994126350 hasConcept C2780696404 @default.
• W1994126350 hasConcept C42228675 @default.
• W1994126350 hasConcept C511782168 @default.
• W1994126350 hasConcept C518104683 @default.
• W1994126350 hasConcept C544153396 @default.
• W1994126350 hasConcept C549387045 @default.
• W1994126350 hasConcept C71240020 @default.
• W1994126350 hasConcept C8010536 @default.
• W1994126350 hasConceptScore W1994126350C115624301 @default.
• W1994126350 hasConceptScore W1994126350C161790260 @default.
• W1994126350 hasConceptScore W1994126350C178790620 @default.
• W1994126350 hasConceptScore W1994126350C179104552 @default.
• W1994126350 hasConceptScore W1994126350C185592680 @default.
• W1994126350 hasConceptScore W1994126350C2777164566 @default.
• W1994126350 hasConceptScore W1994126350C2777716191 @default.
• W1994126350 hasConceptScore W1994126350C2780696404 @default.
• W1994126350 hasConceptScore W1994126350C42228675 @default.
• W1994126350 hasConceptScore W1994126350C511782168 @default.
• W1994126350 hasConceptScore W1994126350C518104683 @default.
• W1994126350 hasConceptScore W1994126350C544153396 @default.
• W1994126350 hasConceptScore W1994126350C549387045 @default.
• W1994126350 hasConceptScore W1994126350C71240020 @default.
• W1994126350 hasConceptScore W1994126350C8010536 @default.
• W1994126350 hasIssue "9" @default.
• W1994126350 hasLocation W19941263501 @default.
• W1994126350 hasOpenAccess W1994126350 @default.
• W1994126350 hasPrimaryLocation W19941263501 @default.
• W1994126350 hasRelatedWork W1977054978 @default.
• W1994126350 hasRelatedWork W1982632695 @default.
• W1994126350 hasRelatedWork W2087193027 @default.
• W1994126350 hasRelatedWork W2151559666 @default.
• W1994126350 hasRelatedWork W2324450644 @default.
• W1994126350 hasRelatedWork W2376304445 @default.
• W1994126350 hasRelatedWork W2951644071 @default.
• W1994126350 hasRelatedWork W2952342847 @default.
• W1994126350 hasRelatedWork W4250454288 @default.
• W1994126350 hasRelatedWork W2627418729 @default.
• W1994126350 isParatext "false" @default.
• W1994126350 isRetracted "false" @default.
• W1994126350 magId "1994126350" @default.
• W1994126350 workType "article" @default.