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- W1994156797 abstract "Several palladium catalysts supported on ZnO with different loadings and dispersions have been prepared, characterized, pretreated, and tested for the selective hydrogenation of small amounts of 1,3-butadiene in 1-butene. Hydrogen treatment at temperatures above 423 K caused a marked decrease in catalytic activity and a simultaneous increase in selectivity for reduction of butadiene primarily to olefins. Such treatment also caused partial reduction of the ZnO support which resulted in the formation of PdZn intermetallic phases (XRD results). XPS measurements suggested that the Pd crystallites were decorated with reduced Zn metal which significantly decreased the availability of the Pd adsorption sites, as determined by hydrogen and carbon monoxide chemisorption. Alternate oxidation and temperature-programmed reduction cycles could distinguish between the formation of (PdO)S and oxidation of the reduced Zn. Even though the overall activity was decreased after high-temperature exposure to hydrogen, the turnover frequency for the smaller number of active sites remained virtually unchanged. Moreover, the activation energy and reaction orders were not altered. High-temperature reduction also decreased the trans/cis-2-butene ratio formed from the butadiene: this may reflect slow interconversion between the syn and anti conformation of the 1,3-butadiene adsorbed on the Zn-decorated surface. These experiments have identified some of the important roles of the support and pretreatment conditions on the performance of such catalysts." @default.
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- W1994156797 date "1993-06-01" @default.
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- W1994156797 title "Hydrogenation of 1-Butene and 1,3-Butadiene Mixtures over Pd/ZnO Catalysts" @default.
- W1994156797 doi "https://doi.org/10.1006/jcat.1993.1164" @default.
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